resources

  • Publication
By Gross and co-workers on natural and modified sophorolipids
  1. Koh, A., Wong, A., Quinteros, A., Desplat, C., & Gross, R. (2016). Influence of Sophorolipid Structure on Interfacial Properties of Aqueous-Arabian Light Crude and Related Constituent Emulsions. Journal of the American Oil Chemists' Society, 1-13.
  2. Koh, Amanda; Gross, Richard (2016) “A versatile family of sophorolipid esters: Engineering surfactant structure for stabilization of lemon oil-water interfaces” Colloids and Surfaces, A: Physicochemical and Engineering Aspects 507, 152-163
  3. Koh, Amanda; Gross, Richard (2016) “Molecular editing of sophorolipids by esterification of lipid moieties: Effects on interfacial properties at paraffin and synthetic crude oil-water interfaces” Colloids and Surfaces, A: Physicochemical and Engineering Aspects 507, 170-181.
  4. Koh, Amanda; Linhardt, Robert J.; Gross, Richard (2016) “Effect of Sophorolipid n-Alkyl Ester Chain Length on Its Interfacial Properties at the Almond Oil-Water Interface” Langmuir, 32(22), 5562-5572.
  5. Peng, Yifeng; Totsingan, Filbert; Meier, Michael A. R.; Steinmann, Mark, Wurm, Frederik; Kho, Amanda; Gross, Richard A. “Sophorolipids: Expanding structural diversity by ring-opening cross-metathesis” European Journal of Lipid Science and Technology (2015)  117(2), 217-228. 
  6. Peng, Yifeng; Munoz-Pinto, Dany J.; Chen, Mingtao; Decatur, John; Hahn, Mariah; Gross, Richard A. “Poly(sophorolipid) Structural Variation: Effects on Biomaterial Physical and Biological Properties” Biomacromolecules 15(11), 4214-4227 (2014).
  7. Peng, Yifeng; Decatur, John; Meier, Michael A. R. and Gross, Richard A. “Ring-Opening Metathesis Polymerization of a Naturally Derived Macrocyclic Glycolipid, Macromolecules, 46(9), 3293-3300 (2013).  
  8. Sleiman J.N., Kohlhoff S.A., Roblin P.A., Wallner S., Gross R., Hammerschlag M.R., Bluth M.H. “Sophorolipids as Antimicrobials” Ann. Clin. Lab Sci 39(1) 60-63.
  9. Zini, E., Gazzano, M., Scandola, M., Wallner, S.R. and Gross, R. A. Glycolipid biomaterials: Solid-state properties of a poly(sophorolipid). Macromolecules 42(20): 7463-7468 (2008).
  10. Fu, S.L., Wallner, S.R., Bowne, W.B., Hagler, M.D., Zenilman, M.E., Gross, R.A. and Bluth, M.H. Sophorolipids and their derivatives are lethal against human pancreatic cancer cells. Journal of Surgical Research 148 (1): 77-82 (2008).
  11. Bluth, M.H., Fu, S.L., Fu, A., Stanek, A., Smith-Norowitz, T.A., Wallner, S.R., Gross, R.A., Nowakowski, M. and Zenilman, M.E. Sophorolipids decrease asthma severity and ova-specific IgE production in a mouse asthma model. Journal of Allergy and Clinical Immunology 121 (2): Pages: S2-S2, Supplement: Suppl. 1, Meeting Abstract: 6 (FEB 2008) 
  12. Hardin, R., Pierre, J., Schulze, R., Mueller, C. M., Fu, S. L., Wallner, S. R., Stanek, A., Shah, V., Gross, R. A., Weedon, J., Nowakowski, M., Zenilman, M. E. and Bluth, M. H. Sophorolipids improve sepsis survival: Effects of dosing and derivatives. Journal of Surgical Research 142 (2): 314-319 (2007).
  13. Fu, S. L., Mueller, C., Lin, Y. Y., Viterbo, D., Pierre, J., Shah, V., Gross, R., Schulze, R. and Zenilman, M. Sophorolipid treatment decreases LIPS induced inflammatory responses and NO production in macrophages. Journal of the American College of Surgeons 205 (3): S44-S44 (2007).
  14. Hagler, M., Smith-Norowitz, T. A., Chice, S., Wallner, S. R., Viterbo, D., Mueller, C. M., Gross, R., Nowakowski, M., Schulze, R., Zenilman, M. E. and Bluth, M. H., Sophorolipids decrease IgE production in U266 cells by downregulation of BSAP (Pax5), TLR-2, STAT3 and IL-6. Journal of Allergy and Clinical Immunology 119 (1): S263-S263 (2007).
  15. Felse, P. A., Shah, V., Chan, J., Rao, K. J. and Gross, R. A. Sophorolipid biosynthesis by Candida bombicola from industrial fatty acid residues. Enzyme and Microbial Technology 40 (2): 316-323 (2007)
  16. Gao, W., Hagver, R., Shah, V., Xie, W., Gross, R. A., Ilker, M. F., Bell, C., Burke, K. A. and Coughlin, E. B. Glycolipid polymer synthesized from natural lactonic sophorolipids by ring-opening metathesis polymerization. Macromolecules 40(2): 145-147 (2007).
  17. Bluth, M.H., Kandil, E., Mueller, C.M., Shah, V., Lin, Y.Y., Zhang, H., Dresner, L., Lempert, L., Nowakowski, M., Gross, R.A., Schulze, R. and Zenilman, M.E. Sophorolipids block lethal effects of septic shock in rats in a cecal ligation and puncture model of experimental sepsis. Critical Care Medicine 34 (1): 188-195 (2006)
  18. Mueller, C.M., Viterbo, D., Murray, P.J., Shah, V., Gross, R.A., Schulze, R., Zenilman, M.E. and Bluth, M.H. Sophorolipid treatment decreases inflammatory cytokine expression in an in vitro model of experimental sepsis. Faseb Journal 20 (4): A204-A204 Part 1, (2006).
  19. Azim, A., Shah, V., Doncel, G.F., Peterson, N., Gao, W. and Gross, R.A. Amino acid conjugated sophorolipids: A new family of biologically active functionalized glycolipids. Bioconjugate Chemistry 17 (6): 1523-1529 (2006).
  20. Shah V, Doncel GF, Seyoum T, Eaton KM, Zalenskaya I, Hagver R, Azim A, Gross R. Sophorolipids, microbial glycolipids with anti-human immunodeficiency virus and sperm-immobilizing activities. Antimicrobial Agents and Chemotherapy; 49 (10); 4093-4100 (2005).
  21. Zhang, L., Somasundaran, P., Singh, S. K., Felse, A. P., Gross, R.A. Synthesis and interfacial properties of sophorolipid derivatives Colloids and Surfaces A: Physicochem.Eng. Aspects; 240; 75-82 (2004)
  22. Zhou, S., Xu, Chang.., Wang, J., Gao, W., Akhverdiyeva., Shah, V., Gross, R. A. Supramolecular Assembles of a Naturally Derived Sopholipid. Langmuir; 20; 7926-7932 (2004)
  23. Singh, S,K, Felse, A. P., Nunez, A., Foglia, T.A. and Gross, R.A. Regioselective Enzyme-Catalyzed Synthesis of Sophorolipid Esters, Amides and Multifunctional Monomers. J. Org. Chem.; 68; 5466-5477 (2003)
  24. V Guilmanov, A Ballistreri, G Impallomeni, R.A. Gross, “Oxygen Transfer Rate and Sophorose Lipid Production by Candida bombicola”, Biotechnol. and Bioeng; 77(5), 489-494 (2002)
  25. Peng, Yifeng; Decatur, John; Meier, Michael A. R. and Gross, Richard A. “Ring-Opening Metathesis Polymerization of a Naturally Derived Macrocyclic Glycolipid, Macromolecules, 46(9), 3293-3300 (2013).  
  26. Sleiman J.N., Kohlhoff S.A., Roblin P.A., Wallner S., Gross R., Hammerschlag M.R., Bluth M.H. “Sophorolipids as Antimicrobials” Ann. Clin. Lab Sci 39(1) 60-63.
  27. Zini, E., Gazzano, M., Scandola, M., Wallner, S.R. and Gross, R. A. Glycolipid biomaterials: Solid-state properties of a poly(sophorolipid). Macromolecules 42(20): 7463-7468 (2008).
  28. Fu, S.L., Wallner, S.R., Bowne, W.B., Hagler, M.D., Zenilman, M.E., Gross, R.A. and Bluth, M.H. Sophorolipids and their derivatives are lethal against human pancreatic cancer cells. Journal of Surgical Research 148 (1): 77-82 (2008).
  29. Bluth, M.H., Fu, S.L., Fu, A., Stanek, A., Smith-Norowitz, T.A., Wallner, S.R., Gross, R.A., Nowakowski, M. and Zenilman, M.E. Sophorolipids decrease asthma severity and ova-specific IgE production in a mouse asthma model. Journal of Allergy and Clinical Immunology 121 (2): Pages: S2-S2, Supplement: Suppl. 1, Meeting Abstract: 6 (FEB 2008) 
  30. Hardin, R., Pierre, J., Schulze, R., Mueller, C. M., Fu, S. L., Wallner, S. R., Stanek, A., Shah, V.,
  31. Gross, R. A., Weedon, J., Nowakowski, M., Zenilman, M. E. and Bluth, M. H. Sophorolipids improve sepsis survival: Effects of dosing and derivatives. Journal of Surgical Research 142 (2): 314-319 (2007).
  32. Fu, S. L., Mueller, C., Lin, Y. Y., Viterbo, D., Pierre, J., Shah, V., Gross, R., Schulze, R. and Zenilman, M. Sophorolipid treatment decreases LIPS induced inflammatory responses and NO production in macrophages. Journal of the American College of Surgeons 205 (3): S44-S44 (2007).
  33. Hagler, M., Smith-Norowitz, T. A., Chice, S., Wallner, S. R., Viterbo, D., Mueller, C. M., Gross, R., Nowakowski, M., Schulze, R., Zenilman, M. E. and Bluth, M. H., Sophorolipids decrease IgE production in U266 cells by downregulation of BSAP (Pax5), TLR-2, STAT3 and IL-6. Journal of Allergy and Clinical Immunology 119 (1): S263-S263 (2007).
  34. Felse, P. A., Shah, V., Chan, J., Rao, K. J. and Gross, R. A. Sophorolipid biosynthesis by Candida bombicola from industrial fatty acid residues. Enzyme and Microbial Technology 40 (2): 316-323 (2007)
  35. Gao, W., Hagver, R., Shah, V., Xie, W., Gross, R. A., Ilker, M. F., Bell, C., Burke, K. A. and Coughlin, E. B. Glycolipid polymer synthesized from natural lactonic sophorolipids by ring-opening metathesis polymerization. Macromolecules 40(2): 145-147 (2007).
  36. Bluth, M.H., Kandil, E., Mueller, C.M., Shah, V., Lin, Y.Y., Zhang, H., Dresner, L., Lempert, L., Nowakowski, M., Gross, R.A., Schulze, R. and Zenilman, M.E. Sophorolipids block lethal effects of septic shock in rats in a cecal ligation and puncture model of experimental sepsis. Critical Care Medicine 34 (1): 188-195 (2006)
  37. Mueller, C.M., Viterbo, D., Murray, P.J., Shah, V., Gross, R.A., Schulze, R., Zenilman, M.E. and Bluth, M.H. Sophorolipid treatment decreases inflammatory cytokine expression in an in vitro model of experimental sepsis. Faseb Journal 20 (4): A204-A204 Part 1, (2006).
  38. Azim, A., Shah, V., Doncel, G.F., Peterson, N., Gao, W. and Gross, R.A. Amino acid conjugated sophorolipids: A new family of biologically active functionalized glycolipids. Bioconjugate Chemistry 17 (6): 1523-1529 (2006).
  39. Shah V, Doncel GF, Seyoum T, Eaton KM, Zalenskaya I, Hagver R, Azim A, Gross R. Sophorolipids, microbial glycolipids with anti-human immunodeficiency virus and sperm-immobilizing activities. Antimicrobial Agents and Chemotherapy; 49 (10); 4093-4100 (2005).
  40. Zhang, L., Somasundaran, P., Singh, S. K., Felse, A. P., Gross, R.A. Synthesis and interfacial properties of sophorolipid derivatives Colloids and Surfaces A: Physicochem.Eng. Aspects; 240; 75-82 (2004)
  41. Zhou, S., Xu, Chang.., Wang, J., Gao, W., Akhverdiyeva., Shah, V., Gross, R. A. Supramolecular Assembles of a Naturally Derived Sopholipid. Langmuir; 20; 7926-7932 (2004)
  42. Singh, S,K, Felse, A. P., Nunez, A., Foglia, T.A. and Gross, R.A. Regioselective Enzyme-Catalyzed Synthesis of Sophorolipid Esters, Amides and Multifunctional Monomers. J. Org. Chem.; 68; 5466-5477 (2003)
  43. V Guilmanov, A Ballistreri, G Impallomeni, R.A. Gross, “Oxygen Transfer Rate and Sophorose Lipid Production by Candida bombicola”, Biotechnol. and Bioeng; 77(5), 489-494 (2002)


By Gross and co-workers on w-hydroxyfatty acids and corresponding lactones

  1. Hu, Jing; Jin, Zhennan; Chen, Tzu-Yin; Polley, Jennifer D.; Cunningham, Michael F.; Gross, Richard A. “Anionic Polymerizable Surfactants from Biobased ω-​Hydroxy Fatty Acids” Macromolecules 47(1), 113-120 (2014). 
  2. Celli, Annamaria; Marchese, Paola; Sullalti, Simone; Cai, Jiali; Gross, Richard A. “Aliphatic/aromatic copolyesters containing biobased ω-hydroxyfatty acids: Synthesis and structure-property relationships” Polymer, 54(15), 3774-3783 (2013).  
  3. Liu, Chen; Liu, Fei; Cai, Jiali; Xie, Wenchun; Long, Timothy E.; Turner, S. Richard; Lyons, Alan; Gross, Richard A. Polymers from Fatty Acids: Poly(ω-hydroxyl tetradecanoic acid) Synthesis and Physico-Mechanical Studies Biomacromolecules, 12(9), 3291-3298 (2011).
  4. Cai, Jiali; Hsiao, Benjamin S.; Gross, Richard A. Real-Time Structure Changes during Uniaxial Stretching of Poly(ω-pentadecalactone) by in Situ Synchrotron WAXD/SAXS Techniques Macromolecules , 44(10), 3874-3883 (2011) .
  5. 5 Lu, Wen-Hua; Ness, Jon E.; Xie, Wen-Chun; Zhang, Xiao-Yan; Minshull, Jeremy; Gross, Richard A. “Biosynthesis of Monomers for Plastics from Renewable Oils” Journal of the American Chemical Society, 132(43), 15451-15455 (2010). 
  6. Focarete, Maria Letizia; Gualandi, Chiara; Scandola, Mariastella; Govoni, Marco; Giordano, Emanuele; Foroni, Laura; Valente, Sabrina; Pasquinelli, Gianandrea; Gao, Wei; Gross, Richard A. “Electrospun scaffolds of a polyhydroxyalkanoate consisting of ω-hydroxylpentadecanoate repeat units: fabrication and in vitro biocompatibility studies” Journal of Biomaterials Science, Polymer Edition, 21(10), 1283-1296 (2010). 
  7. Cai, Jiali; Liu, Chen; Cai, Minmin; Zhu, Jie; Zuo, Feng; Hsiao, Benjamin S.; Gross, Richard A. “Effects of molecular weight on poly(ω-pentadecalactone) mechanical and thermal properties” Polymer , 51(5), 1088-1099 (2010) . 
  8. 8  Cai J.L., Hsiao B.S., Gross R.A.; “Polypentadecalactone prepared by lipase catalysis: crystallization kinetics and morphology” Polymer International 58(8): 944-953 ( 2009).
  9. 9 Jiang, Z. Z., Azim, H., Gross, R. A., Focarete, M. L. and Scandola, M., Lipase-catalyzed copolymerization of omega-pentadecalactone with p-dioxanone and characterization of copolymer thermal and crystalline properties. Biomacromolecules 8 (7): 2262-2269 (2007).
  10. 10 Ceccorulli, G.; Scandola, M.; Kumar, A.; Kalra, B.; Gross, R. A., “Cocrystallization of Random Copolymers of -Pentadecalactone and -Caprolactone Synthesized by Lipase Catalysis” Biomacromolecules; 6(2); 902-907 (2005).
  11. 11 Kalra, B.; Kumar, A.; Gross, R. A.; Baiardo, M.; Scandola, M. “Chemoenzymatic Synthesis of New Brush Copolymers Comprising Poly( -pentadecalactone) with Unusual Thermal and Crystalline Properties” Macromolecules; 37(4); 1243-1250 (2004).